附註:Includes bibliographical references and index.
Cover -- Table of Contents -- Chapter 1 Introduction, Brief History and Basic Concepts -- 1.1 The Phenomenon of Electrochemical Promotion -- 1.2 Basic Concepts and Terminology -- 1.3 Structure of This Book -- Chapter 2 Promotion in Heterogeneous Catalysis -- 2.1 Introduction -- 2.2 Chemisorption and Catalytic Kinetics -- 2.3 Catalytic Kinetics and Promoters -- 2.4 Interactions of Adsorbates Acting as Promoters or Poisons with Catalyst Surfaces -- 2.5 Adsorption on Surfaces Modified by Electropositive or Electronegative Promoters -- 2.6 Catalytic Activity on Surfaces Modified by Promoters or Poisons -- 2.7 Summarizing Comments and Rules -- Chapter 3 Solid Electrolytes, Catalysis and Spillover -- 3.1 Solid Electrolytes -- 3.2 Solid Electrolyte Potentiometry (SEP) -- 3.3 Electrocatalytic Operation of Solid Electrolyte Cells -- 3.4 Spillover-backspillover Phenomena -- Chapter 4 Electrochemical Promotion of Catalytic Reactions -- 4.1 Experimental Setup -- 4.2 Catalyst-Electrode Film Characterization -- 4.3 A NEMCA Experiment: Galvanostatic and Potentiostatic Transients -- 4.4 Catalyst Work Function Variation with Potential in Solid Electrolyte Cells -- 4.5 Definitions, Phenomenology and Key Aspects of Electrochemical Promotion -- 4.6 Prediction of the Magnitude of the Faradaic Efficiency -- 4.7 Synopsis of the Phenomenology: Reactions Studied so Far -- Chapter 5 Origin of NEMCA -- 5.1 Problems and Methods -- 5.2 A Galvanostatic NEMCA Transient Revisited -- 5.3 Analysis of Rate Time Constants During Galvanostatic Transients. -- 5.4 Work Function and Electrochemical Promotion -- 5.5 Temperature Programmed Desorption (TPD) -- 5.6 Solid Electrolyte Cyclic Voltammetry -- 5.7 AC Impedance Spectroscopy -- 5.8 XPS Investigations -- 5.9 UPS Investigations -- 5.10 SERS Investigations -- 5.11 PEEM Investigations -- 5.12 Scanning Tunelling Microscopy -- 5.13 Quantum Mechanical Calculations -- 5.14 The Effective Double Layer -- Chapter 6 Rules and Modeling of Promotion -- 6.1 Elec
摘要:This book describes the phenomenology, theory and potential applications of the phenomenon of electrochemical promotion, where electrochemically induced ion spillover activates and controls heterogeneous catalysis. The origin of electrochemical promotion is discussed in light of a plethora of surface spectroscopic and electrochemical techniques. Electrochemical and classical promotion are compared, their common rules are identified and promotional kinetics are rigorously modeled and compared with experiment.
