附註:Includes bibliographical references and indexes.
Cover -- Preface -- Table of Contents -- Chapter 1. Metal/Solution Interface: An Experimental Approach -- I. Introduction -- II. Molecular Approach to the Metal/Solution Interface -- III. The Thermodynamic Approach to the Metal/Solution Interface -- References -- Chapter 2. Quantum Mechanical Treatments in Electrode Kinetics -- I. Introduction -- II. Continuum Theory of Electron Transfer Reactions -- III.?G♯ (Continuum) and the Inverted Region -- IV. Molecular Models of Electron Transfer Reactions at Electrodes. -- V. Molecular Models of Bond-Breaking Ion and Electron Transfer Reactions -- VI. Electronic Transmission Coefficient K -- VII. Proton Transfer Reactions -- VIII. Solvent Dynamic Effects on ET Reactions at Electrodes -- References -- Chapter 3. Molecular Dynamic Simulations in Interfacial Electrochemistry -- I. Introduction -- II. The Water/Metal Interface -- III. Ionic Adsorption and Solvation at the Water/Metal Interface -- IV. Interfacial Electron Transfer Reactions -- V. Processes at the Liquid/Liquid Interface -- VI. Conclusions and Outlook -- References -- Chapter 4. Underpotential Deposition on Single-Crystal Metals -- I. Introduction -- II. Underpotential Deposition on Single-Crystal Electrodes -- III. Mechanism of Underpotential Deposition -- IV. Electrocatalysis on Electrodes Modified by Underpotential Deposition. -- V. Miscellaneous -- VI. Conclusion -- References -- Chapter 5. Automated Methods of Corrosion Measurement -- I. Introduction -- II. Corrosion Measurements by Titration -- III. Imaging Corrosion by Scanning Probe Microscopy -- IV. Critical Pitting Temperature -- V. Applications of the Electrochemical Hydrogen -- References -- Cumulative Author Index for Numbers 1 ... 31 -- Cumulative Title Index for Numbers 1 ... 31.
摘要:This is the latest volume of the series praised by JACS for its "high standards," and by Chemistry and Industry for rendering a "valuable service." Experts from academic and industrial laboratories worldwide present: -- Experimental results from the last decade of interfacial studies -- A surprising quantum mechanical treatment of electrode processes -- Recent work in molecular dynamic simulations, which confirms some earlier modelistic approaches and also breaks new ground -- An in-depth look at underpotential deposition on single crystal metals, and -- The practical matter of automated corrosion measurement
