附註:Includes bibliographical references and index.
Cover -- Table of Contents -- PREFACE -- CHAPTER 1. HYDRODESULFURIZATION AND HYDRODENITROGENATION -- 1.1. Introduction -- 1.2. The Hydrodesulfurization Reaction -- 1.3. The Hydrodenitrogenation Reaction -- References -- CHAPTER 2. COORDINATION AND ACTIVATION OF THIOPHENES IN METAL COMPLEXES -- 2.1. Introduction -- 2.2. n1S-Bonded metal thiophene complexes -- 2.3. n2(C=C)-Bonded metal thiophene complexes -- 2.4. n3(S9C=C)-Bonded metal thiophene complexes -- 2.5. n4-Bonded metal thiophene complexes -- 2.6. n5-Bonded metal thiophene complexes -- 2.7. n6-Bonded metal benzothiophene and dibenzothiophene complexes -- 2.8. Conclusions and further comments -- References -- CHAPTER 3. HYDROGENATION REACTIONS -- 3.1 Introduction -- 3.2. Homogeneous Hydrogenation of Aromatic Hydrocarbons -- 3.3 Homogeneous Hydrogenation of Heteroaromatic Hydrocarbons -- References -- CHAPTER 4 RING OPENING, HYDROGENOLYSIS AND DESULFURIZATION OF THIOPHENES BY METAL COMPLEXES -- 4.1. Introduction -- 4.2. Stoichiometric ring opening, hydrogenolysis, and desulfurization of thiophenes -- 4.3. Homogeneous Catalytic Hydrogenolysis and Hydrodesulfurization of Thiophenes -- 4.4. Further remarks on the relations between homogeneous and heterogeneous hydrogenolysis and HDS of thiophenes -- References -- CHAPTER 5. ACTIVATION OF HYDROGEN ON METAL COMPLEXES WITH SULFIDE LIGANDS AND RELATED COORDINATION CHEMISTRY OF H2S -- 5.1 Introduction -- 5.2 Hydrogen activation on dinuclear complexes containing sulfido or disulfido ligands -- 5.3 Hydrogen activation on mononuclear Ti=S and Ti(n2S2) complexes -- 5.4. Reactions of H2S with metal complexes -- 5.5 Conclusions and remarks -- References -- CHAPTER 6. MODELING HYDRODENITROGENATION -- 6.1 Introduction -- 6.2 Binding Modes of N-Heterocycles in Transition Metal Complexes -- 6.3 Reactions of N-Heterocycles in Transition Metal Complexes -- 6.4 C-N Bond Activation of Amines, Imines, and Amides by Transition Metal Complexes -- 6.5. Final Remarks -- References --
摘要:The hydrodesulfurization and hydrodenitrogenation of petroleum and refinery cuts have been in continuous development and in industrial practice for several decades. New environmental constraints regarding the quality of fuels has produced a renaissance of this field as the search for novel solution to this problem intensifies. This volume reviews the structures, bonding and reactions of metal complexes of the thiophenes and other HDS-related molecules, as well as of some HDN-related organinitrogen compounds. This chemistry is analyzed in the context of modeling some key species and reactions implicated in HDS and HDN catalysis. Many parallels are drawn between organometallic and surface chemistry, and homogeneous and heterogeneous catalysis. The book should be of value to chemists and chemical engineers in academic and industrial environments, since the organometallic modeling approach emerges as a powerful tool to aid in the understanding of the structures and reaction mechanisms occurring in real systems, and in the design of novel HDS and HDN catalysts.
