附註:Includes bibliographical references (pages 879-888) and index.
Preface; Table of Contents; Detailed Table of Contents; 1 Introduction; 1.1 Introduction; 1.2 Basis of Separation; 1.3 Adsorbents; 1.3.1 Alumina; 1.3.2 Silica gel; 1.3.3 Activated Carbon; 1.3.4 Zeolite; 1.4 Adsorption Processes; 1.5 The Structure of the Book; 2 Fundamentals of Pure Component Adsorption Equilibria; 2.1 Introduction; 2.2 Langmuir Equation; 2.2.1 Basic Theory; 2.2.2 Isosteric Heat of Adsorption; 2.3 Isotherms based on the Gibbs Approach; 2.3.1 Basic Theory; 2.3.2 Linear Isotherm; 2.3.3 Volmer Isotherm; 2.3.4 Hill-deBoer Isotherm; 2.3.5 Fowler-Guggenheim Equation.
2.3.6 Harkins-Jura Isotherm2.3.7 Other Isotherms from Gibbs Equation; 2.4 Multisite Occupancy Model of Nitta; 2.4.1 Estimation of the Adsorbate-Adsorbate Interaction Energy; 2.4.2 Special Case; 2.4.3 Extension to Multicomponent Systems; 2.5 Mobile Adsorption Model of Nitta et al.; 2.6 Lattice Vacancy Theory; 2.7 Vacancy Solution Models (VSM); 2.7.1 VSM-Wilson Model; 2.7.2 VSM-Floiy-Huggin Model; 2.7.3 Isosteric Heat of Adsorption; 2.8 2-D Equation of State (2-D EOS) Adsorption Isotherm; 2.9 Concluding Remarks; 3 Practical Approaches of Pure Component Adsorption Equilibria; 3.1 Introduction.
3.2 Empirical isotherm equations3.2.1 Freundlich Equation; 3.2.2 Sips Equation (Langmuir-Freundlich); 3.2.3 Toth Equation; 3.2.4 Unilan equation; 3.2.5 Keller, Staudt and Toth's Equation; 3.2.6 Dubinin-Radushkevich Equation; 3.2.7 Jovanovich Equation; 3.2.8 Temkin Equation; 3.2.9 Summary of Empirical Equations; 3.3 BET (Brunauer, Emmett and Teller) isotherm and modified BET isotherm; 3.3.1 BET Equation; 3.3.2 Differential heat; 3.3.3 BDDT (Brunauer, Deming, Deming, Teller) Classification; 3.3.4 Comparison between the van der Waals adsorption and the Capillary Condensation.
3.3.5 Other Modified Versions of the BET Equation3.3.6 Aranovich's Modified BET Equations; 3.4 Harkins-Jura, Halsey Isotherms; 3.5 Further Discussion on the BET Theory; 3.5.1 Critical of the BET theory; 3.5.2 Surface with Adsorption Energy Higher than Heat of Liquefaction; 3.6 FHH Multilayer Equation; 3.7 Redhead's Empirical Isotherm; 3.8 Summary of Multilayer Adsorption Equation; 3.9 Pore volume and pore size distribution; 3.9.1 Basic Theory; 3.10 Practical Approaches for the Pore Size Distribution Determination; 3.10.1 Wheeler and Schull's method; 3.10.2 Cranston and Inkley's (CI) method.
3.10.3 De Boer Method3.11 Assessment of Pore Shape; 3.11.1 Hysteresis Loop; 3. 11.2 t-Method; 3.11.3 The s Method; 3.12 Conclusion; 4 Pure Component Adsorption in Microporous Solids; 4.1 Introduction; 4.1.1 Experimental Evidence of Volume Filling; 4.1.2 Dispersive Forces; 4.1.3 Micropore Filling Theory; 4.2 Dubinin Equations; 4.2.1 Dubinin-Radushkevich (DR) Equation; 4.2.2 Dubinin-Astakhov Equation; 4.2.3 Isosteric Heat of Adsorption and Heat of Immersion; 4.3 Theoretical Basis of the Potential Adsorption Isotherms; 4.4 Modified Dubinin Equations for Inhomogeneous Microporous Solids.
摘要:This book covers topics of equilibria and kinetics of adsorption in porous media. Fundamental equilibria and kinetics are dealt with for homogeneous as well as heterogeneous particles. Five chapters of the book deal with equilibria and eight chapters deal with kinetics. Single component as well as multicomponent systems are discussed. In kinetics analysis, we deal with the various mass transport processes and their interactions inside a porous particle. Conventional approaches as well as the new approach using Maxwell-Stefan equations are presented. Various methods to measure diffusivity, such.
