附註:Includes bibliographical references and index.
1. What is thermodynamics? -- 2. Defining our terms -- 3. The first law of thermodynamics -- 4. The second law of thermodynamics -- 5. Getting data -- 6. Some simple applications -- 7. Ideal solutions -- 8. Fugacity and activity -- 9. The equilibrium constant -- 10. Real solutions -- 11. The phase rule -- 12. Redox reactions -- 13. Equations of state -- 14. Solid solutions -- 15. Electrolyte solutions -- 16. Rock-water systems -- 17. Phase diagrams -- 18. Process modeling -- App. A. Constants and numerical values -- App. B. Standard state properties -- App. C. Some mathematics -- App. D. How to use SUPCRT92 -- App. E. Computer programs -- App. F. Symbols used -- App. G.A short history of thermodynamic constraints.
摘要:Thermodynamics deals with energy levels and the transfer of energy between states of matter, and is therefore fundamental to all branches of science. This new edition provides a relatively advanced treatment of the subject, specifically tailored for the interests of the Earth sciences. The first four chapters explain all necessary concepts, using a simple graphical approach. Throughout the rest of the book the author emphasizes the use of thermodynamics to construct mathematical simulations of real systems. This helps to make the many abstract concepts acceptable. Many computer programs are mentioned and used throughout the text, especially SUPCRT92, a widely used source of thermodynamic data. An associated website includes links to useful information sites and computer programs and problem sets. Building on the more elementary material in the first edition, this textbook will be ideal for advanced undergraduate and graduate students in geology, geochemistry, geophysics and environmental science.
