附註:Includes bibliographical references and index.
Cover -- List of Contributors -- Preface -- Table of Contents -- Chapter 1. Principles of Temporal and Spatial Pattern Formation in Electrochemical Systems -- I. Introduction -- II. Principles of Temporal Pattern Formation -- III. Principles of Spatial Pattern Formation -- IV. Summary -- Chapter 2. Electrochemical Impedance Spectroscopy and its Applications -- I. Introduction -- II. Impedance Measurements -- III. Impedance of Faradaic Reactions in the Presence of Diffusion -- IV. Impedance of a Faradaic Reaction Involving Adsorption of Reacting Species -- V. Impedance of Solid Electrodes -- VI. Conditions for "Good" Impedances -- VII. Modeling of Experimental Data -- VIII. Instrumental Limitations -- IX. Conclusion -- References -- Chapter 3. Establishing the Link Between Multistep Electrochemical Reaction Mechanisms and Experimental Tafel Slopes -- I. Introduction -- II. Chemical Kinetics -- III. Simple One-Step, One-Electron Electrochemical Kinetics -- IV. Sequence of Consecutive Electrochemical Reactions Involving a Single Rate-Determining Step -- V. Modifications to the Consecutive Electrochemical Reaction -- VI. Tafel Slopes Greater than 118 mV dec ... 1 -- VII. Application to the Processes of Aluminum Deposition and Dissolution -- VIII. Conclusions -- Acknowledgments -- References -- Chapter 4. Electro-Osmotic Dewatering of Clays, Soils, and Suspensions -- I. Introduction -- II. An Outline of Electro-Osmotic Dewatering -- III. Phenomenological Equations -- IV. The Electrochemical Approach to Electro-Osmotic Dewatering: Helmholtz ... Smoluchowski Relation -- V. Electro-Osmotic Dewatering: Some Experimental Aspects -- VI. Applications of Electro-Osmotic Dewatering -- VII. Appendix -- Acknowledgments -- References -- Chapter 5. The Effect of Magnetic Fields on Electrochemical Processes -- I. Introduction -- II. Magnetic Field Effects on Electrolyte Behavior -- III. Magnetic Field Effects on Surface Morphology -- IV. The Magnetic Field Effect on Electrode React
摘要:Recognized experts present incisive analysis of both fundamental and applied problems in this continuation of a highly acclaimed series. Topics discussed include: A thorough and mathematical treatment of periodic phenomena, with consideration of new theories about the transition between `order' and `chaos'; Impedance spectroscopy as applied to the study of kinetics and mechanisms of electrode processes; The use of stoichiometric numbers in mechanism analysis; The electro-osmotic dewatering of clays with important implications for the processing of industrial waste and geotechnical; stabilization; Magnetic effects in electrolytic processes and the electrolytic Hall effect; and The computer analysis and modeling of mass transfer and fluid flow. These authoritative studies will be invaluable for researchers in engineering, electrochemistry, analytical chemistry, materials science, physical chemistry, and corrosion science.
